Motivated by the recent successful application of physics-informed neural networks (PINNs) to solve Boltzmann-type equations [S. Jin, Z. Ma, and K. Wu, J. Sci. Comput., 94 (2023), pp. 57], we provide a rigorous error analysis for PINNs in approximating the solution of the Boltzmann equation near a global Maxwellian. The challenge arises from the nonlocal quadratic interaction term defined in the unbounded domain of velocity space. Analyzing this term on an unbounded domain requires the inclusion of a truncation function, which demands delicate analysis techniques. As a generalization of this analysis, we also provide proof of the asymptotic preserving property when using micro-macro decomposition-based neural networks.
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