This paper proposes a new approach for the calibration of material parameters in elastoplastic constitutive models. The calibration is posed as a constrained optimization problem, where the constitutive evolution equations serve as constraints. The objective function quantifies the mismatch between the stress predicted by the model and corresponding experimental measurements. To improve calibration efficiency, a novel direct-adjoint approach is presented to compute the Hessian of the objective function, which enables the use of second-order optimization algorithms. Automatic differentiation (AD) is used for gradient and Hessian computations. Two numerical examples are employed to validate the Hessian matrices and to demonstrate that the Newton-Raphson algorithm consistently outperforms gradient-based algorithms such as L-BFGS-B.
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