We investigate the convergence of a backward Euler finite element discretization applied to a multi-domain and multi-scale elliptic-parabolic system, derived from the Doyle-Fuller-Newman model for lithium-ion batteries. We establish optimal-order error estimates for the solution in the norms $l^2(H^1)$ and $l^2(L^2(H^q_r))$, $q=0,1$. To improve computational efficiency, we propose a novel solver that accelerates the solution process and controls memory usage. Numerical experiments with realistic battery parameters validate the theoretical error rates and demonstrate the significantly superior performance of the proposed solver over existing solvers.
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