Diffuse domain methods (DDMs) have garnered significant attention for approximating solutions to partial differential equations on complex geometries. These methods implicitly represent the geometry by replacing the sharp boundary interface with a diffuse layer of thickness $\varepsilon$, which scales with the minimum grid size. This approach reformulates the original equations on an extended regular domain, incorporating boundary conditions through singular source terms. In this work, we conduct a matched asymptotic analysis of a DDM for a two-sided problem with transmission Robin boundary conditions. Our results show that, in one dimension, the solution of the diffuse domain approximation asymptotically converges to the solution of the original problem, with exactly first-order accuracy in $\varepsilon$. We provide numerical simulations that validate and illustrate the analytical result. Furthermore, for the Neumann boundary condition case, we show that the associated energy functional of the diffuse domain approximation $\Gamma-$convergences to the energy functional of the original problem, and the solution of the diffuse domain approximation strongly converges, up to a subsequence, to the solution of the original problem in $H^1(\Omega)$, as $\varepsilon \to 0$.
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