Markov Chain Monte Carlo methods for sampling from complex distributions and estimating normalization constants often simulate samples from a sequence of intermediate distributions along an annealing path, which bridges between a tractable initial distribution and a target density of interest. Prior work has constructed annealing paths using quasi-arithmetic means, and interpreted the resulting intermediate densities as minimizing an expected divergence to the endpoints. We provide a comprehensive analysis of this 'centroid' property using Bregman divergences under a monotonic embedding of the density function, thereby associating common divergences such as Amari's and Renyi's ${\alpha}$-divergences, ${(\alpha,\beta)}$-divergences, and the Jensen-Shannon divergence with intermediate densities along an annealing path. Our analysis highlights the interplay between parametric families, quasi-arithmetic means, and divergence functions using the rho-tau Bregman divergence framework of Zhang 2004,2013.
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