La0.7Ba0.3MnO3 (LBMO):Agx (x = 0.0, 0.1, 0.2, 0.3, and 0.4) composites are synthesized by solid-state reaction route, the final sintering temperatures are varied from 1300 (LBMO1300Ag) to 1400 0C (LBMO1400Ag), and their physical properties are compared as a function of temperature and Ag content. All samples are crystallized in single phase accompanied by some distortion in main structural phase peaks at higher angles with increase in silver content. Though the lattice parameters (a, c) decrease, the b increases slightly with an increase in Ag content. The scanning electron micrographs (SEM) showed better grains morphology in terms of size and diffusion of grain boundaries with an increase in Ag content. In both LBMO1300Ag and LBMO1400Ag series the metal insulator transition (TMI) and accompanied paramagnetic-ferromagnetic transition (TC) temperatures are decreased with increase in Ag content. The sharpness of MI transition, defined by temperature coefficient of resistance (TCR), is improved for Ag added samples. At a particular content of Ag(0.3), the TMI and TC are tuned to 300K and maximum magneto-resistance at 7Tesla applied field (MR7T) of up to 55% is achieved at this temperature, which is more than double to that as observed for pure samples of the both 1300 and 1400 0C series at same temperature. The MR7T is further increased to above 60% for LBMOAg(0.4) samples, but is at 270K. The MR7T is measured at varying temperatures of 5, 100, 200, 300, and 400K in varying fields from +/- 7 Tesla, which exhibits U and V type shapes. Summarily, the addition of Ag in LBMO improves significantly the morphology of the grains and results in better physical properties of the parent manganite system.
翻译:La0.70BA0.3MNO3 (LBMO): Agx (x = 0.0, 0.1, 0.2, 0.3, 0.4) 复合材料由固态反应途径合成,最后的交点温度从1300(LBMO1300Ag)到14000C(LBMO1400Ag)不等,其物理特性由温度和Ag含量的函数来比较。所有样品都以单阶段的形式结晶,同时在高温度角度的主要结构阶段峰值出现某些扭曲,而银含量增加。尽管拉蒂参数(a, c) 减少, b 随Ag含量增加而略有增加。扫描电子B 显像仪(SEM) 显示谷物形态从1300(LB1300Ag)到颗粒边界的传播都有改善。在LB1300AMRMMM(T)中, 金属的温度变化在TI(TI) 和磁性变变变色(TC) 温度在AGMR(T) 的变色温度上都有改善,在TRMMMMM(T) 样本中是特定的变色。