In this study we present a detailed ab initio analysis of the magnetic properties of VSe2 . Ab initio calculations in the so-called 1T structure yield a ferromagnetic phase as most stable, with a magnetic moment of about 0.6 {\mu} B /V. According to our calculations, and based on the Stoner criterion for itinerant ferromagnets, this ferromagnetic state is on the verge of instability. We have modeled ab initio the charge density wave state reported in the literature. This introduces a periodic lattice distortion leading to a supercell with periodicity 4a x 4a x 3c (4a x 4a for the monolayer) in which we have fully relaxed the atomic positions. We demonstrate that this structural rearrangement causes a strong reduction in the density of states at the Fermi level and the ground state of the system becomes non-magnetic. Experimental evidences that report a magnetic signal need to be understood on the light of this finding.
翻译:在本研究中,我们对VSe2的磁性进行了详细的初始分析。在所谓的 1T 结构中,Ab 初始计算得出了一个最稳定的铁磁级,其磁性瞬间大约为0.6 ymu} B/V。根据我们的计算,并基于流动铁磁网的斯通尔标准,这种铁磁状态处于不稳定的边缘。我们从文献中报道的电荷密度波状态开始就进行了模拟。这引入了一种周期4a x 4a x 3c(单层为4a x 4a 4a) 的定期变形,导致一个周期周期4的超级细胞,我们完全放松了原子位置。我们证明,这种结构重新排列导致费尔米级各州的密度大幅下降,而系统地面状态也变得非磁性。根据这一发现,需要了解报告磁信号的实验证据。