In this study, a novel semi-implicit second-order temporal scheme combined with the finite element method for space discretization is proposed to solve the coupled system of infiltration and solute transport in unsaturated porous media. The Richards equation is used to describe unsaturated flow, while the advection-dispersion equation (ADE) is used for modeling solute transport. The proposed approach is used to linearize the system of equations in time, eliminating the need of iterative processes. A free parameter is introduced to ensure the stability of the scheme. Numerical tests are conducted to analyze the accuracy of the proposed method in comparison with a family of second-order iterative schemes. The proposed numerical technique based on the optimal free parameter is accurate and performs better in terms of efficiency since it offers a considerable gain in computational time compared to the other methods. For reliability and effectiveness evaluation of the developed semi-implicit scheme, four showcase scenarios are used. The first two numerical tests focus on modeling water flow in heterogeneous soil and transient flow in variably saturated zones. The last numerical tests are carried out to simulate the salt and nitrate transport through unsaturated soils. The simulation results are compared with reference solutions and laboratory data, and demonstrate the effectiveness of the proposed scheme in simulating infiltration and solute transport through unsaturated soils.
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