Variational integrators for Euler--Lagrange equations and Hamilton's equations are a class of structure-preserving numerical methods that respect the conservative properties of such systems. Lie group variational integrators are a particular class of these integrators that apply to systems which evolve over the tangent bundle and cotangent bundle of Lie groups. Traditionally, these are constructed from a variational principle which assumes fixed position endpoints. In this paper, we instead construct Lie group variational integrators with a novel Type II variational principle on the cotangent bundle of a Lie group which allows for Type II boundary conditions, i.e., fixed initial position and final momenta; these boundary conditions are particularly important for adjoint sensitivity analysis, which is the motivating application in our paper. In general, such Type II variational principles are only globally defined on vector spaces or locally defined on general manifolds; however, by left translation, we are able to define this variational principle globally on cotangent bundles of Lie groups. By developing the continuous and discrete Type II variational principles over Lie groups, we construct a structure-preserving Lie group variational integrator that is both symplectic and momentum-preserving. Subsequently, we introduce adjoint systems on Lie groups, and show how these adjoint systems can be used to perform geometric adjoint sensitivity analysis for optimization problems on Lie groups. Finally, we conclude with two numerical examples to show how adjoint sensitivity analysis can be used to solve initial-value optimization problems and optimal control problems on Lie groups.
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