Large Language Models (LLMs) have shown strong capabilities in language understanding and reasoning across diverse domains. Recently, there has been increasing interest in utilizing LLMs not merely as assistants in optimization tasks, but as primary optimizers, particularly for network-structured combinatorial problems. However, before LLMs can be reliably deployed in this role, a fundamental question must be addressed: Can LLMs iteratively manipulate solutions that consistently adhere to problem constraints? In this work, we propose a systematic framework to evaluate the capability of LLMs to engage with problem structures. Rather than treating the model as a black-box generator, we adopt the commonly used evolutionary optimizer (EVO) and propose a comprehensive evaluation framework that rigorously assesses the output fidelity of LLM-based operators across different stages of the evolutionary process. To enhance robustness, we introduce a hybrid error-correction mechanism that mitigates uncertainty in LLMs outputs. Moreover, we explore a cost-efficient population-level optimization strategy that significantly improves efficiency compared to traditional individual-level approaches. Extensive experiments on a representative node-level combinatorial network optimization task demonstrate the effectiveness, adaptability, and inherent limitations of LLM-based EVO. Our findings present perspectives on integrating LLMs into evolutionary computation and discuss paths that may support scalable and context-aware optimization in networked systems.
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