We employ the Bayesian improved cross entropy (BiCE) method for rare event estimation in static networks and choose the categorical mixture as the parametric family to capture the dependence among network components. At each iteration of the BiCE method, the mixture parameters are updated through the weighted maximum a posteriori (MAP) estimate, which mitigates the overfitting issue of the standard improved cross entropy (iCE) method through a novel balanced prior, and we propose a generalized version of the expectation-maximization (EM) algorithm to approximate this weighted MAP estimate. The resulting importance sampling distribution is proved to be unbiased. For choosing a proper number of components $K$ in the mixture, we compute the Bayesian information criterion (BIC) of each candidate $K$ as a by-product of the generalized EM algorithm. The performance of the proposed method is investigated through a simple illustration, a benchmark study, and a practical application. In all these numerical examples, the BiCE method results in an efficient and accurate estimator that significantly outperforms the standard iCE method and the BiCE method with the independent categorical distribution.
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