Using dominating sets to separate vertices of graphs is a well-studied problem in the larger domain of identification problems. In such problems, the objective is typically to separate any two vertices of a graph by their unique neighbourhoods in a suitably chosen dominating set of the graph. Such a dominating and separating set is often referred to as a \emph{code} in the literature. Depending on the types of dominating and separating sets used, various problems arise under various names in the literature. In this paper, we introduce a new problem in the same realm of identification problems whereby the code, called the \emph{open-separating dominating code}, or the \emph{OSD-code} for short, is a dominating set and uses open neighbourhoods for separating vertices. The paper studies the fundamental properties concerning the existence, hardness and minimality of OSD-codes. Due to the emergence of a close and yet difficult to establish relation of the OSD-codes with another well-studied code in the literature called the open locating dominating codes, or OLD-codes for short, we compare the two on various graph classes. Finally, we also provide an equivalent reformulation of the problem of finding OSD-codes of a graph as a covering problem in a suitable hypergraph and discuss the polyhedra associated with OSD-codes, again in relation to OLD-codes of some graph classes already studied in this context.
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