无机纳米片与石墨烯的可控组装及其纳米复合体的光化学电化学性能

项目名称： 无机纳米片与石墨烯的可控组装及其纳米复合体的光化学电化学性能

项目编号： No.51272030

项目类型： 面上项目

立项/批准年度： 2013

项目学科： 一般工业技术

项目作者： 杨晓晶

作者单位： 北京师范大学

项目金额： 80万元

中文摘要： 本项目提出系统研究金属氧化物（如层状二氧化锰）和金属氢氧化物（如层状双金属氢氧化物）等无机纳米片，与石墨烯/氧化石墨烯纳米片作为纳米晶体建筑构件的组装行为；旨在以性能为导向，制备不同结构的纳米复合体，从而发挥无机纳米片在电化学、发光、催化等性能方面的优势，实现它们与石墨烯的性能互补与优化，并进一步赋予纳米复合材料以新的功能。研究集中于：①通过重点考察无机纳米片种类、助剂（包括絮凝剂、分散剂、稳定剂、模板等）、还原（方式和还原剂种类、引入次序）等因素，探索异体组装的反应过程和机理；②研究复合体组成、结构与相关性能的关系，为设计具有特定结构和功能的异体组装纳米复合体提供依据，实现复合体结构的可控调节；③探索纳米复合体作为一类新型材料在锂离子电池、光催化、光致发光等方面的应用。本研究涉及材料物理和化学、结晶学、软化学、胶体化学、电化学、光化学等领域，将增加这些方面的知识积累，具有理论和应用价值。

中文关键词： 无机纳米片；纳米复合材料；石墨烯复合材料；电化学；光化学

英文摘要： A systematic investigation on the allogeneic assembly behaviors of inorganic nanosheets (IONS) including metal oxides and hydroxides (such as manganese dioxide, layered double hydroxides) and graphene/graphene oxide nanosheets, as nanocrystal building blocks, is proposed in this project. Based on the investigation, this project aimed at the performance-oriented fabrication of differently structural nanocomposites, in which the IONS could play the advantageous role in the electrochemistry, luminescence, catalytic performance, etc., fulfilling the complementarity and performance optimization of IONS and graphene, and further giving nanocomposites with novel features. The work will focus on the followings. (1) Through studying on factors of, mainly, the IONS species, the additives including flocculants, dispersing agents, stabilizers, templates, etc., and reduction (methods employed, the reductant species and applying orders), the reaction process and mechanism will be explored for the allogeneic assemblies; (2) by researching the relationship between the composition，structure and the performance of assembled nanocomposites, the basis will be provided for the design of nanocomposites with specific structures and functions, in order to achieve a adjustment of the nanocomposite structures; and (3) the potential appli

英文关键词： inorganic nanosheets；nanocomposites；graphene composites；electrochemistry；photochemistry