This paper presents a novel approach for computing substructure characteristic modes. This method leverages electromagnetic scattering matrices and spherical wave expansion to directly decompose electromagnetic fields. Unlike conventional methods that rely on the impedance matrix generated by the method of moments (MoM), our technique simplifies the problem into a small-scale ordinary eigenvalue problem, improving numerical dynamics and computational efficiency. We have developed analytical substructure characteristic mode solutions for a scenario involving two spheres, which can serve as benchmarks for evaluating other numerical solvers. A key advantage of our method is its independence from specific MoM frameworks, allowing for the use of various numerical methods. This flexibility paves the way for substructure characteristic mode decomposition to become a universal frequency technique.
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