功能化有序介孔酚醛树脂的可控合成及其应用于固载有机小分子催化剂的研究

项目名称： 功能化有序介孔酚醛树脂的可控合成及其应用于固载有机小分子催化剂的研究

项目编号： No.51273112

项目类型： 面上项目

立项/批准年度： 2013

项目学科： 一般工业技术

项目作者： 张昉

作者单位： 上海师范大学

项目金额： 80万元

中文摘要： 发展高效且可回收和重复利用的高分子催化材料的设计合成是当前国内外高分子材料领域的研究热点。本项目针对传统高分子载体由于比表面积低和孔径小，造成催化活性位负载量低、分布不均匀以及传质阻力大，导致高分子催化剂的催化效率低和稳定性差的瓶颈问题，拟以功能化有序介孔酚醛树脂的可控合成及其应用于固载有机小分子催化剂的研究为重点，系统深入地研究氨基介孔酚醛树脂的化学组分和结构形貌的调控方法和制备规律；设计氨基介孔酚醛树脂固载有机小分子催化剂（(S)-二苯基脯氨醇三甲基硅醚）合成路线，建立具有高活性和选择性且化学结构稳定的介孔酚醛树脂固载有机小分子催化剂的理论模型；研究介孔酚醛树脂固载有机小分子催化剂在手性不对称合成的反应机理及其化学组成、结构和形貌与催化性能之间的构效关系和内在联系，探索提高高分子固载催化剂催化性能的基本途径，为建立新型高分子固载催化剂的设计合成提供系统的科学基础和技术指导。

中文关键词： 介孔；酚醛树脂；功能化；固载；非均相催化剂

英文摘要： The development of recoverable and reusable polymer catalysts with high catalytic efficiency is of considerable significance and has been a mainstay in the field of polymer materials research. Despite the fact that a large number of traditional polymer supports have been reported, they usually displayed relatively low catalytic activity and selectivity compared to the homogeneous catalysts owing to their low surface area, small pore size and the increased diffusion resistance. This project addresses the design, synthesis and characterization of novel functionalized ordered mesoporous phenol-formaldehyde resin and its application for immobilizing (S)-diphenylprolinol silyl ether organocatalyst. We propose to explore the catalytic performances of these novel mesoporous polymeric organocatalysts in the asymmetric reactions and further test their durability and subsequent reusable efficiency. Meanwhile, we investigate to engineer the structure and chemistry of the catalysts to achieve a better catalytic performance and fundamentally understanding their influence on the catalytic reactions. Based on various characterizations, the correlation of the catalytic properties to the physical structure, chemical composition and surface properties of the mesoporous resin-based organocatalysts will be discussed. This success

英文关键词： Mesoporous；Phenol-formaldehyde resin；Functionalization；Immobilization；Heterogeneous catalyst