暖白光LED用低光衰高显色性Lu3Al5-x(Si/B)xO12-yNy:Ce荧光粉的研究

项目名称： 暖白光LED用低光衰高显色性Lu3Al5-x(Si/B)xO12-yNy:Ce荧光粉的研究

项目编号： No.51472087

项目类型： 面上项目

立项/批准年度： 2015

项目学科： 一般工业技术

项目作者： 李会利

作者单位： 华东师范大学

项目金额： 78万元

中文摘要： 通过离子取代进行微结构调控合成的新型Lu3Al5-x(Si/B)xO12-yNy:Ce荧光粉，不但发射色彩可控裁剪，且光效和热稳定性都远远优于同结构的YAG:Ce材料，在低色温和高显色性暖白光LED中表现出巨大应用潜力，但其发光性能提高的内在机制尚不清楚。本项目以新型Lu3Al5-x(Si/B)xO12-yNy:Ce荧光粉为研究对象，综合利用微观结构分析和第一性原理的模拟计算，研究取代离子占据LuAG晶格的具体位置及取代后发光离子中心的局部微结构变化；通过化学组成设计、制备工艺优化、精细结构解析和发光性能的系统研究，揭示其相互之间的关系，阐明其发光机制，深化对晶态材料宏观发光特性与发光中心微观功能基元本质的认识，进而提出实现微结构调控新型Lu3Al5-x(Si/B)xO12-yNy:Ce荧光体发光性能剪裁设计和可控制备的有效途径，为研制低色温和高显色指数的暖白光LED奠定基础。

中文关键词： 稀土发光材料；Lu3Al5-x(Si/B)xO12-yNy:Ce；光致发光；构效关系；白光LED

英文摘要： The emission colors of LuAG:Ce consisting of the similar crystal structure with YAG:Ce can be tailored through the substitution of ions to control its microstructure. Moreover, the luminescent efficiency and thermal stability of the synthesized novel Lu3Al5-x(Si/B)xO12-yNy:Ce phosphors are much better than those of YAG-based oxynitride phosphors, which has a potential application on warm white LEDs with a low correlated color temperature (CCT) and a high color-rendering index (CRI). However, little attention has been paid on investigating the modification of optical properties of LuAG:Ce by controlling the microstructure. Also it is still unknown that why the optical properties of Lu3Al5-x(Si/B)xO12-yNy:Ce phosphors are largely improved. In this project, novel Lu3Al5-x(Si/B)xO12-yNy:Ce phosphors will be synthesized by the incorporation of N3? into the LuAG host to change its microstructure. The occupied site of substitution ions in LuAG host and the local microstructural variation around activators will be carefully investigated and simulated by HAADF-STEM, EXAFS, XANES, neutron diffraction and the first principles,respectively. By investigating the effect of chemical composition variation and preparation process on lattice structure and optical properties, the relationship and interaction mechanism of the chemical composition, crystal structure and luminescence property will be disclosed, and the luminescent mechanism will be illuminated. Finally, the optical properties of LuAG:Ce phosphors can be efficiently designed and tailored by the replacement of ions. The present work will lay the foundation for developing warm-white LEDs with high luminescent efficiency, a high CRI and a low CCT.

英文关键词： phosphor;Lu3Al5-x(Si/B)xO12-yNy:Ce;Photoluminescence;Relationship between microstructure and optical properties;White LEDs