Traditional language model alignment methods, such as Direct Preference Optimization (DPO), are limited by their dependence on static, pre-collected paired preference data, which hampers their adaptability and practical applicability. To overcome this limitation, we introduce Self-Augmented Preference Optimization (SAPO), an effective and scalable training paradigm that does not require existing paired data. Building on the self-play concept, which autonomously generates negative responses, we further incorporate an off-policy learning pipeline to enhance data exploration and exploitation. Specifically, we employ an Exponential Moving Average (EMA) model in conjunction with a replay buffer to enable dynamic updates of response segments, effectively integrating real-time feedback with insights from historical data. Our comprehensive evaluations of the LLaMA3-8B and Mistral-7B models across benchmarks, including the Open LLM Leaderboard, IFEval, AlpacaEval 2.0, and MT-Bench, demonstrate that SAPO matches or surpasses established offline contrastive baselines, such as DPO and Odds Ratio Preference Optimization, and outperforms offline self-play methods like SPIN. Our code is available at https://github.com/yinyueqin/SAPO
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