低介电常数BNw/Si3N4复合透波材料研究

项目名称： 低介电常数BNw/Si3N4复合透波材料研究

项目编号： No.51202097

项目类型： 青年科学基金项目

立项/批准年度： 2013

项目学科： 无机非金属材料学科

项目作者： 赵林

作者单位： 景德镇陶瓷学院

项目金额： 25万元

中文摘要： 以三聚氰胺(C3N6H6)和硼酸(H3BO3)为主要原料，采用溶胶-凝胶法低温常压合成氮化硼晶须前驱体，利用氮化工艺和除碳工艺制备出形貌规则、表面光洁度高、长径比大、介电常数和介电损耗角正切值低等优良物理化学性能的氮化硼晶须(BNw)。通过在氮化硅（Si3N4）基体中添加BNw，采用等静压成型和气压烧结工艺，制备出高强度、高断裂韧性、高介电性能的BNw/Si3N4复合透波材料。利用分散剂对BNw进行表面处理和分散，并采用等静压成型工艺获得分散均匀、致密的陶瓷坯体。采用气压烧结工艺并添加烧结助剂，可以制备出形状复杂、力学性能和介电性能优异的透波复合材料。本项目通过实验确定最佳的BNw制备工艺，研究BNw含量及分散工艺、气压烧结温度制度和压力对复合透波材料力学和介电性能的影响。分析复合透波材料的微观结构以及烧结过程中物相的演变，并对实验体系的烧结机理、强韧化机理和透波机理进行探讨。

中文关键词： BNw/Si3N4复合透波材料；介电性能；烧结机理；增韧机理；透波机理

英文摘要： BN whisker precursors will be synthesized with melamine (C3N6H6) and boric acid (H3BO3) as raw materials at low temperature and pressure by the sol-gel method. BN whiskers (BNw) with excellent properties of regular morphology, smooth surface, large aspect ratio, low dielectric constant and dielectric loss tangent will be prepared by nitridation and decarbonization process. BNw/Si3N4 wave-transparent composites with high bending strength, high fracture toughness and high dielectric property will be prepared using isostatic pressing and gas pressure sintering process by adding toughening agent BNw to Si3N4. Well dispersed and dense ceramic bodies will be acquired by surface treatment，dispersion of BNw and isostatic pressing process. BNw/Si3N4 wave-transparent composites with complex shape, excellent mechanical and dielectric properties can be prepared by gas pressure sintering process with sintering aids. The optimal BNw preparation process will be determined, the BNw content and dispersion process, the influence of sintering temperature system and pressure of gas pressure sintering on mechanical and dielectric properties of BNw/Si3N wave-transparent composites will be investigated. The microstructure and phase transition during sintering will be analysized.Meanwhile,the sintering mechanism, toughening mechanism a

英文关键词： BNw/Si3N4wave-transparent composites；Dielectric properties；Sintering mechanism；Toughening mechanism；Wave-transparent mechanism