MNWs-CNTs/PET复合耐磨柔性透明导电膜制备、界面结构及特性研究

项目名称： MNWs-CNTs/PET复合耐磨柔性透明导电膜制备、界面结构及特性研究

项目编号： No.51274106

项目类型： 面上项目

立项/批准年度： 2013

项目学科： 矿业工程

项目作者： 沈湘黔

作者单位： 江苏大学

项目金额： 80万元

中文摘要： 因铟资源短缺及ITO脆性等问题，首次提出优化组合不同长度和特性的电纺金属纳米丝（MNWs）和碳纳米管（CNTs），以聚对苯二甲酸乙二醇酯（PET）为基体，通过表面功能化，采用浸涂和后处理技术形成MNWs-CNTs复合导电网络，制备耐磨、高可见光透射率、低方块电阻和高热导率膜材料。研究MNWs的电纺-热还原过程，建立MNWs特性与其制备过程参数之间的关系；探索和认识MNWs溶液分散、MNWs和CNTs表面功能化、MNWs-CNTs与PET结合状态、可见光和载流子在复合膜中的行为、复合膜的摩擦学行为等；建立复合膜组成、制备过程、结构与其物理化学性能的关系；开发出高性能、低成本MNWs-CNTs/PET复合耐磨柔性透明导电膜的制备技术。研究在复合膜形成过程中MNWs和CNTs之间、复合导电网络和PET基体之间等的界面结构，揭示其对复合膜微观结构和性能的影响规律，发展纳米复合先进材料科学与技术。

中文关键词： 柔性透明导电膜；银纳米线；导电网络；界面结构；耐弯折性

英文摘要： Due to shortage of indium resources and brittleness of ITO, the wear-resistant, flexible, transparent, conducting films of metal nanowires (MNWs)-carbon nanotubes (CNTs) composite networks polyethylene terephthalate (PET)are prepared by the dip-coating and post-treatment process with optimized MNWs and CNTs and they are characterized with a high wear-resistance, a high visible light transparency, a low square resistance and an excellent heat conductance.The electrospinning and thermal reduction process is used to fabricate MNWs and the relation will be established between the MNWs characteristics and processing factors.By engineering of MNWs, CNTs and PET surfaces, the dispersion of MNWs and CNTs in solutions is investigated, leading a good interface strength between the PET substrate and networks of MNWs and CNTs. Then the behavior of tribology,visible light and electric carriers can be studied for the composite films. Based on the optimization of the processes for MNWs preparation, dispersion of MNWs and CNTs, dip-coating and post-treatment of composite films, the relationship can be realized among the composition, process, structure and properties.Consequently,the novel process for highly wear-resistant, flexible, transparent, conducting films of MNWs-CNTs/PET with a low cost can is developed. The interface s

英文关键词： Flexible transparent conductive film；Silver nanowire；Conductive network；Interfacial structure；Bendability