松香基两亲分子在功能化溶剂中的自组装

项目名称： 松香基两亲分子在功能化溶剂中的自组装

项目编号： No.31300486

项目类型： 青年科学基金项目

立项/批准年度： 2014

项目学科： 农业科学

项目作者： 宋冰蕾

作者单位： 江南大学

项目金额： 23万元

中文摘要： 松香作为我国特色的林业资源，在表面活性剂领域有着重要应用。本项目将松香酸骨架的特征结构与表面活性剂科学的基本问题相结合，深入研究松香基两亲分子在羟基功能化溶剂中的自组织规律和聚集体形貌，重点关注松香基两亲分子疏水基的刚性结构和手性中心的作用。主要研究内容包括新型松香基两亲分子和功能化溶剂的设计合成、松香基两亲分子的自组织和以松香基两亲分子自组织结构为模板的有序介孔材料的制备。通过在功能化溶剂中松香基两亲分子聚集体的形成、转变等性能的表征，揭示松香基两亲分子独特的自组织形式，为松香在新技术领域的应用奠定理论基础。

中文关键词： 松香表面活性剂；离子液晶；自组织；相互作用；

英文摘要： As our country's featured forestry resources, rosin has important applications in surfactant field. In order to challenge the fundamental problems in surfactant science, the unique structure of rosin acid is considered in this project. The self-assembly principles and aggregate morphologies of rosin-based amphiphiles in hydroxyl group functionalized solvents are intensively studied. The effects of rigid structure and chiral center in the rosin-based amphiphiles are especially focused. The main research contents include the design and synthesis of novel rosin-based amphiphiles and functional solvents, the self-assembly of rosin-based amphiphiles and the preparation of ordered mesoporous materials. By investigating the aggregate formation and transformation of rosin-based amphiphiles, the unique self-assembly principles of rosin-based amphiphiles would be revealed. The theories obtained in this study are also beneficial for the applications of rosin in new technology fields.

英文关键词： rosin-based surfactant；ionic liquid crystal；self-assembly；molecular interaction；