多功能有机膦酸盐的结构规律与性能

项目名称： 多功能有机膦酸盐的结构规律与性能

项目编号： No.20801055

项目类型： 青年科学基金项目

立项/批准年度： 2009

项目学科： 化学工业

项目作者： 傅瑞标

作者单位： 中国科学院福建物质结构研究所

项目金额： 24万元

中文摘要： 多功能有机膦酸盐的结构规律与性能的研究是一个具有原创性和实际应用前景的项目。本项目选择和设计合成含叔胺、COOH、OH、吡啶和PO3H2等多功能有机膦酸，以4,4’联吡啶为第二配体及各种尺寸和构型的有机胺为结构导向剂，合成和结构表征了26例新型多功能有机膦酸盐，总结合成条件和多功能有机膦酸盐的结构规律；测定和研究其荧光、荧光敏感、热稳定性和磁性，初步探索结构与性能的关系；取得了有意义的研究成果，完成了预期的研究目标。研究成果共发表SCI论文6篇，其中Dalton Trans. 2篇, CrystEngComm. 2篇和J. Solid State Chem. 2篇。

中文关键词： 多功能;膦酸;结构;性能

英文摘要： The study of structural rules and properties of multi-functional metal phosphonates is an original project, which has a practical prospect of application. 26 new multi-functional metal phosphonates have been synthesized and structural characterized by employing phosphonic acids containing additional functional groups, such as COOH, OH, tertiary amine and pyridine, introducing a various of organic amines as structure-directing agents, as well as 4,4'-bipyridine as a second organic ligand. Synthesis conditions and structural rules for multi-functional metal phosphonates have been summarized. And luminescence, luminescent sensitivity, thermal stability and magnetism of multi-functional metal phosphonates have been investigated. In addition, the relationship of structures and properties has also been summarized. 6 papers based on these research results have been published on SCI journals, including 2 papers on Dalton Trans., 2 papers on CrystEngComm. and 2 papers on J. Solid State Chem..

英文关键词： multi-function;phosphpnic acid;structure;property