新型自燃离子液体推进剂的合成及点火性能研究

项目名称： 新型自燃离子液体推进剂的合成及点火性能研究

项目编号： No.11472251

项目类型： 面上项目

立项/批准年度： 2015

项目学科： 数理科学和化学

项目作者： 张庆华

作者单位： 中国工程物理研究院化工材料研究所

项目金额： 82万元

中文摘要： 以发展绿色双组元液体火箭推进剂为背景，本项目拟开展自燃离子液体的合成及其在双组元液体推进剂中的点火性能研究。通过对阴阳离子骨架结构的合理设计及搭配，发展两类结构新颖的哌嗪类和烯胺类离子液体材料；重点研究离子液体结构与性质、性能之间的内在关系和规律，考察离子液体与强氧化剂之间的自发点火行为，实现高效自燃离子液体推进剂的结构筛选和性能优化，获得最优的离子液体体系。研究离子液体与强氧化剂之间的快速氧化还原反应，探索离子液体的自燃机理，从深层次上揭示离子液体结构与能量密度、点火性能之间的内在关系，为下一步发展高效的自燃离子液体推进剂奠定基础。该研究对于推动绿色液体推进剂材料和离子液体材料研究的交叉融合、丰富材料科学技术内涵、发展新型绿色高性能液体推进剂材料等具有重要意义。

中文关键词： 离子液体；推进剂；点火；合成；性质

英文摘要： Against the background of exploring green liquid rocket bipropellants, the aim of this project is to develop novel hypergolic ionic liquids and to investigate their iginition properties and performance in the liquid bipropellants. Through the rational design and proper pairing of organic cations and anions,two class of novel ionic liquids materials, i.e., piperazinium-based ionic liquids and enamine-based ionic liquids, will be designed and synthesized. The emphases is to study the correlations of ionic liquid structure with their properties and performance and to investigate the spontaneous ignition behaviour between ionic liquids and strong oxidizers.By virtue of structural and property optimization,some ionic liquids with excellent integrated performance will be obtained.Moreover,with the aim of obtaining a further understanding of the relationships between structure,energy density and ignition property,the oxidation-reduction reaction between ionic liquids and oxidizers will be studied, while the mechanism of spontaneous combustion will be explored, which can provide the basis for developing high-performance green rocket propellants.This study has important significance for promoting the cross-comprehension between green liquid propellant materials and ionic liquids,the enrichment of the intension of material science and the development of novel green high-performance liquid propellant materials.

英文关键词： ionic liquid;propellant;ignition;synthesis;property