多级孔分子筛主体—纳米粒子客体复合材料的可控制备及催化性能研究

项目名称： 多级孔分子筛主体—纳米粒子客体复合材料的可控制备及催化性能研究

项目编号： No.21501095

项目类型： 青年科学基金项目

立项/批准年度： 2016

项目学科： 数理科学和化学

项目作者： 许冬冬

作者单位： 南京师范大学

项目金额： 20万元

中文摘要： 本项目制备以多级孔分子筛为主体或载体，以金属、金属氧化物或硫化物等为客体催化剂的功能化复合材料，利用沸石骨架的刚性特征控制纳米粒子在其内部的生长；尝试考察多级孔分子筛的骨架结构、形貌、孔隙率等，以及客体纳米粒子在主体材料中的负载和分布情况，来研究和对比客体催化材料在相应催化反应中不同的催化特性；考察不同种类客体催化剂在特定催化反应中的催化性能，努力寻找出复合材料的结构特征和催化性能之间存在的规律，以期为新型纳米催化剂的制备和开发提供一定的借鉴与指导。开发出一系列具有优异催化性能的复合材料，并致力探索其在实际工业催化中的应用可能和前景。

中文关键词： 分级孔道；无机纳米粒子；复合材料；催化性能；沸石

英文摘要： This project aims to prepare the functional composite materials, which are composed of hierarchical porous zeolite as the host and metallic nanoparticles (metal, metal oxide or sulfide and so on) as the guest. Owning to the rigid zeolitic framework, the metallic nanoparticles will be restricted in the domain of mesopores and the morphologies will be well controlled. Through the studying and comparison of the zeolitic framework type, morphologies and porosity of the hierarchical porous zeolites, the loading capacity and distribution of metallic nanoperticles inside the porous host，the catalytic properties of these composite materials will be tested in different catalytic reactions. The different type of metallic nanoparticles will be also investigated in detail in the specific catalytic reactions. We try to find out the general laws between the structural characteristics and catalytic properties，in order to provide a feasible reference and guidance for the preparation and development of novel nano-catalysts。 We aim to develop a series of novel composite materials which possess excellent catalytic properties and devote ourselves to explore their application in practical industrial catalysis.

英文关键词： hierarchical pores;inorganic nanoparticles;composite materials;catalytic performance;zeolites