Chemical characterization of PM2.5 bound species during the Diwali fireworks in Delhi: An insight from source apportionment and airborne hazardous elements

Diwali is among the most important Indian festivals, and elaborate firework displays mark the festivities in the evening. This study assesses the impact of Diwali on the concentration, composition, and sources of ambient PM2.5. The total PM2.5 concentrations were observed to rise by ~16 times their pre-firework levels, while each of the elements, organics, and black carbon were augmented by a factor of 12.3, 1.6, and 2.3, respectively. Concentration levels of species like K, Al, Sr, Ba, S, and Bi displayed distinct peaks during the firework event and were identified as tracers for the same. The average concentrations of potential carcinogens like As, exceeded US EPA screening levels for industrial air by a factor of ~9.6, while peak levels reached up to 16.1 times the screening levels. The source apportionment study, undertaken using positive matrix factorization, revealed the fireworks to account for 95% of the total elemental PM2.5 during Diwali. The resolved primary organic emissions, too, were enhanced by a factor of ~8 during Diwali. Delhi has encountered serious haze events following Diwali in recent years, this study highlights that it is the biomass burning emissions rather than the fireworks that dominate Delhi's air quality in the days following Diwali.